Look for bright red colored, shiny and unwrinkled fresh red chillies.
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NutriBuddy™ 
Description
Fresh red chilli is an erect, branched, shrub-like herb with fruits, in the genus Capsicum, a member of the nightshade family, Solanaceae. They have shiny, deep red colored skin and are used in a variety of cuisines to add a fiery spiciness to them. Fresh red chilli can be used fresh, or in dried powdered form as well.